McCaw will become the first All Black to win 100 caps after missing last Friday's 83-7 victory over Japan with a calf problem as one of four changes.
Carter has overcome his back problem to start at fly-half while Israel Dagg has been selected ahead of Mils Muliaina at full-back.
There is no place in the 22 for Jimmy Cowan with Piri Weepu preferred at scrum-half and Andy Ellis offering cover from the bench.
Adam Thomson switches back to number 8 to accommodate McCaw with Victor Vito dropping out of the squad.
The New Zealand line-up contains 727 caps with three of the XV - Tony Woodcock, McCaw and Carter - also starting the 2007 quarter-final defeat by France.
New Zealand team: I Dagg; C Jane, C Smith, M Nonu, R Kahui; D Carter, P Weepu; T Woodcock, K Mealamu, O Franks, B Thorn, S Whitelock, J Kaino, R McCaw (capt), A Thomson.
Replacements: A Hore, B Franks, A Williams, A Boric, A Ellis, C Slade, S B Williams.
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The entire All Blacks apparel line has been updated for 2013/14. Check out the New Zealand All Blacks polo.
The Nike Tiempo is a solid rugby cleat and one of few styles still made from full-grain natural leather.
The Gilbert Blitz 8S rugby cleat is a great cleat at a great price of $69.99. Get a new pair of cleats today.
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Wear the crest of the British and Irish Lions on your t-shirt. A great look for the summer.
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The All Blacks Performance t-shirt is black with hints of blue from the training jersey. Very Cool.
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The NEW All Blacks 2013/14 jersey has arrived at World Rugby Shop. Dare to wear the colors of the All Blacks.
